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Introduces concepts of chemical reactions. In six 10-minute segments: Steady Unsteadiness (steady-state and closed systems, equilibrium); Dynamic Equilibrium; Reaction Kinetics; Reaction Tendencies (Le...
Discusses the formation of vinyl chloride from 1,2 dichloroethane and the factors which affect yields and rates. Thermodynamics suggests an optimum yield at 600k but the rate of formation at this temperature...
Steps in the development at ICI of a long life carbon-zinc-aluminium hydroxide catalyst for the low-pressure and -temperature synthesis of methanol from hydrogen and carbon monoxide. Investigation of the...
Demonstrates the vital role of chemical and thermodynamic theory in modern chemistry. Examines thermochemical and Born Haber cycles. Demonstrates the importance of structure and chemical behaviour.
The alkaline hydrolysis of a chiral chloride (L)-1 chloro-1-phenyl ethane) is followed polarimetrically to illustrate a unimolecular nucleophilic substitution reaction. Unimolecular and bimolecular...
Establishes the thermodynamic principles governing the favourability of a reaction and shows how these can be used to test the feasibility of reactions designed to produce hydrogen as a fuel for the future.
Covers types of bond fission, inductive and mesomeric effects and the classification of reagents.
Relates energy profiles to reaction types and elementary reaction kinetics.
A film containing computer-generated sequences of the interaction between deuterium ions (D+) and hydrogen deuteride (HD). The sequences, together with other animation, give a full semi-classical treatment...
Deals with examples of substitution and addition reactions classifying each as nucleophilic, electrophilic or free radical and with acidic and basis eliminations.
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